Lead poisoning from pottery glaze and paint
NO form of lead or arsenic may be used in our materials without specific clearance and training from the instructor. Lead is hazardous to breathe, to ingest (eat), and can be released from firing into the air. Finally, any container glazed with these materials may be toxic to eat or drink from because lead can leach into food or drink stored in the vessel. While new pottery sold today in the United States is generally assumed to be safe from lead, occasionally one still reads about cases of pottery that is accidentally sold with dangerous amounts of lead in the glaze. Lead has many very serious effects if ingested. Lead can be absorbed from glazes by acidic food or drink. Lead is not a colorant, but is used to help the glaze melt, so it can be in low fire glaze of any color. One should be particularly cautious about old pottery and pottery purchased in countries while traveling. Inexpensive test kits can now be purchased to test for lead release from paints and pottery glazes. If you need a test kit, do an Internet search for lead check. In paint, lead carbonate was formerly used for white. Lead oxide was a red colorant. Since white could be part of many tints, lead is very common in old paint. Lead has contaminated soil around many old houses where it has washed down the siding by rain. People tracking in dust can poison young children who crawl on the floors. Children with lead in their systems will have a lower lower intelligence and other serious symptoms. The following hazardous materials may be used with care and precautions. Workers must NOT inhale the dust or fumes from them and you must NOT ingest (no eating or drinking in the area of use). Never smoke with traces of these materials on your hands. Most of them are not significantly toxic after proper firing in high fired glazes, but make no assumptions without additional research. Antimony oxide, barium of any form, beryllium, borax, cadmium, selenium, cobalt, colemanite (or gerstley borate), copper, chromium (chrome), lustre preparations, manganese, nickel, potassium dichromate, vanadium, and zinc. While it may be uncommon, I know a potter who was diagnosed with cobalt and cadmium in his system. His illness was rare and difficult to diagnose. He became very ill before being correctly diagnosed. He may have inhaled the toxins in conjunction with smoking while is fingers had toxic residue on them. The court did not find legal proof of negligence on the part of the chemical suppliers. As clay workers and teachers, we need to take responsibility for our own health and that of our students - at least to the extent we are aware of problems. FIRING TOXINS The following materials can liberate toxic fumes while being fired. It is also found that common ball clay contains naturally occurring dioxin and that firing releases the dioxin into the air. Long term breathing of the firing fumes show accumulation in the blood. "Although the number of subjects is small, these results suggest that the dominant route of exposure for case 1 was inhalation of dioxins volatilized during tiring of ceramic pieces in the unvented kilns in the basement of their home." AVOID HOME BASEMENT KILN LOCATIONS Many materials partially volatize (turn to vapor and become airborne) when heated in the kiln. These poisonous gases may include (depending on the materials being fired) antimony, boron, cadmium, dioxin, lead, selenium, zinc, and precious metals. Once airborne you can breath them. Furthermore, they condense on all surfaces they contact. Kilns need to be vented and exhausted to the outdoors. Most vent systems are not good enough to be totally effective. Therefore, I would not locate a kiln in my home or basement of my home. I would locate kilns in outside shelters or in out buildings that are not inhabited. Home duct systems and spaces under doors allow basement air to come into the whole house. If you sleep or work in the same building during the firing you will inhale the toxins from the air. It is possible for toxic heavy metal vapors to condense over time on all the walls, floors, and other surfaces of a home that has a kiln repeatedly fired in the basement. Young children invariably rub their hands on these surfaces and become poisoned when they put their fingers in their mouths. Serious health problems can be caused by just living in a house that has had a kiln firing in the basement. Nobody wants to be knowingly responsible for the retardation of a child's mental development. Locating a kiln in a home basement could damage the brain of a future child whose parents are not aware that there ever was a kiln in this home. See:Alfred Franzblau, et.al. "Case Report: Human Exposure to Dioxins from Clay" Environ Health Perspect. 2008 February; 116(2): 238–242. This is a report regarding a ceramic hobbyist who had elevated blood serum levels of dioxin. The investigators believe that ball clay was the source of the dioxin. They believe that an unvented kiln in her basement "from the early 1960s to the mid-1990s" was the source of the dioxin in her blood. She had two friends who had fired kilns in their garages for the same amount of time and had much lower blood serum levels of dioxins.
REMEDIATION FOR A CONTAMINATED HOUSE top of page If you think a house may be contaminated, test the surfaces for traces of toxins. Many old houses are contaminated because lead was used in paint. Even exterior paint is a problem because it has chalked off and contaminated the earth. This dirt is tracked into the house and children crawl on the floors. Food raised in a garden near the house will contain lead. Fruit trees near the house will produce contaminated fruit. Get a county or state health department to recommend a testing lab. Remediation may be too complicated for a do-it-yourself approach. If all old paint has to be removed, it requires professional experienced workers who know how to protect their own health. The house probably needs to be vacated during remediation. Check the yellow pages and the Internet for qualified professional companies. Check their work with prior clients and appropriate city and state licensing agencies. In some cases the code may allow covering the old paint with new paint. Check health and building codes. Local housing departments have these regulations. If the house has surface toxins from a kiln, it should be less difficult to eliminate risk. Redecorate. Get new curtains. Repaint every wall, refinish every floor, put in new carpet, refinish all doors and woodwork before allowing a child to live there and/or before selling the house. I would use chemical tack cloths to prepare surfaces for refinishing. I would avoid sanding old surfaces because it makes dust. I would use wet cleaning methods. I would avoid using a vacuum unless the vacuum unit is outside with only vacuum pipes and hoses inside. STUDIO ELECTRIC KILNS If electric kilns in studios are fired regularly in the same air being used by the person or persons working in the studio, there could be an air quality issue. See the section above about kilns in basements, and the possibilities of dioxin in ball clay. (2 - Franzblau. et. al.) Historically, clay was always fired outdoors. What if we placed our electric kilns in uninhabited garden sheds? At least kilns should be in a walled-off separate room with lots of outside ventilation or a fan system that removes firing fumes. I have electric kilns in a separate room. I generally fire it at night when I am not in the same building. SCHOOL KILNS School kilns may be too difficult to use if placed in a separate outdoor facility, but it is worth considering for new construction so the logistics can be part of the design of the school. Kilns firing in schools should be tested while firing to be sure fumes do not come into classrooms. Any odor or taste from the kiln that is noticeable in the classroom would be a warning that the vent is not working well enough. The kiln ventilation system should be powerful enough so no air moves from the kiln room to the classroom. Air must be allowed to enter the kiln room so that the vent system can draw out the fumes. The kiln room door can have a permanently open vent or a large space under the door to allow for an air supply. The school ventilation system should not take any air from the kiln room into the school's air system. Vent the kiln fumes outdoors. If you hold a smoking match at the base of the door or at the door vent, you should see the airflow from the classroom into the kiln room. Keep the door closed. Air should not move from the kiln room to the classroom. I was called to a school that had serious odor in the hallways while the kiln was firing. In this case the roof vent was blocked with snow and the kiln vent was blowing the fumes into the false ceiling area above the kiln and it was polluting the rest of the building. The ductwork leaked because the exit vent was blocked. An exterior exhaust fan would keep negative pressure in the duct system and would be less likely to be blocked by snow, bird nests, etc. OUCH! Head Injuries --- BOING ! I use a safety chain. It can be attached to a secure anchor bolt in the ceiling or up high on the wall near the back of the kiln. It is a lightweight metal chain with a hook at the bottom end. I place the chain through the lid handle and hook up the chain. Mine is long enough that I can raise the lid just a crack and hang it from the chain. I like this better than a prop for cooling the kiln because it does not damage the kiln brick like a prop does. Of course depending on the handle means that I need to inspect the handle itself to be sure rust has not weakened the handle's attachment bolts, etc. DUST HAZARDS - top of page Gesundheit Dust from ordinary clay and several other materials contains some free silica that is too fine and heavy to be expelled from the lungs. Over time this can cause fatal silicosis if breathed often enough. Never carelessly produce dust. In 2008, I was contacted by an attorney who was representing a woman who had been diagnosed with pneumoconiosis by a board certified pulmonologist. She had chest x-rays and a lung biopsy. It was determined that she had pneumonoconiosis. They believed that clay dust had been the source of her disease. The doctor had taken a complete life history, and the woman had never been exposed to anything else that could cause her lung scarring. She had inhaled clay dust over 3-4 years in pottery classes she took at a community college. At the end of each semester, she and other students were asked to (and did) sweep the pottery class, and clean pottery cubby holes. She said that the instructor had not cautioned them about the effects of clay dust. To avoid raising dust, we should use only wet cleaning methods. Vacuum sweepers, brooms, and brushes do not filter out the fine problematic particles, but simply make them airborne so they are inhaled easier. Never leave scraps of clay or slip where they are walked on. Warren MacKenzie has worked with clay all his life. While every person's experiences are unique, this statement from MacKenzie gives some perspective on the problem of clay dust.
Some talc and other materials contain impurities of asbestos, which can cause cancer if inhaled. Other materials have a structure somewhat similar to asbestos. This is another reason to avoid making dust and breathing the dust. Dust masks should be used if and when dust cannot be avoided. Dust masks must fit well and they must be specifically designed for very fine dust. Many masks are sold in drug stores that do not qualify. Use only a NIOSH (National Institute for Occupational Safety and Health) approved masks rated for fine toxic dust. They are not effective if they do not fit well. Persons with a beard cannot depend on the effectiveness of a dust mask. Also see: Monona Rossol. "Respirators & Dust Masks, Part 1."Nov/Dec 1999 issue of Clay Times. Respirators & Dust Masks, Part 2 Jan/Feb 2000 issue of Clay Times. (4) I use a sealed clay mixer/pugger so that when it is closed, no dust can escape. It is on wheels. Before I mix clay from dry ingredients, I move it outside. Wood ash from a fireplace can be used as glaze. It is very alkaline and can cause skin damage, rash, and so on. Keep hands out of it. Ball clay contains dioxin. (2)
Knowing what we do today about the its hazards, potters should not use uranium. I heard of a potter whose widow brought suit against a supplier of uranium oxide because she felt her husband's cancer had been caused by uranium. The widow of the supplier told me about the problem. Her husband had not wanted to acquire the uranium for the potter. He had supplied it only after the potter signed a legal release for the supplier, but this did not keep the potter's widow from bringing suit against the company (then owned by the supplier's widow as the supplier had died of heart problems). Beware of old supplies lingering around and being passed from potter to potter or from teacher to teacher. I once discovered a brown paper bag with several pounds of earthy yellowish powder in a school supply cabinet in a high school classroom. When tested with a geiger counter it emitted significant radioactivity. It was uranium oxide apparently still there from a time prior to World War II when it was commonly sold as a glaze colorant. Allergies A few individuals suffer from special allergies to molds that are normally contained in aging clay. These individuals may find it virtually impossible to work indoors with clay. They may have to restrict their involvement to outdoor work during mild weather. Dry Skin - top of page Almost everybody suffers from dryness of skin after working with clay. Creams and lotions after working are recommended. Also, use these liberally before bedtime if more healing is needed. Rubber gloves are used as a prevention. Cold water is less harmful than hot water when throwing because it does not remove natural oils from the skin as much. Back Injuries One of the most common occupational hazards to potters comes from poor lifting habits related to bags of clay, kiln shelves, and so on. Stand close to the your load. Do not reach over for a heavy item. Place feet on both sides of the heavy item, bend the knees and squat down. Lift by straightening the legs. Lift by bending knees while keeping the back straight. Once injured, a back may never heal properly, but there are therapies to help build back some strength. Wrist Injuries Carpal tunnel syndrome and tendon problems can be caused by overuse or misuse of wrists or/and other joints and muscles. If you begin to feel pain while working you have to rest or change the hand positions. If you feel tingling in the hand or arm during the night change the hand positions or stop the activity that causes swelling or muscle constriction of the nerve. In mild cases you can use a splint from the pharmacy to immobilize the wrist during the night until it heals. If throwing on the wheel or wedging is the offending activity, try changing the way it is done. Use the body more and the wrist less. Take regular breaks. Try some hand building. Limit your use of the computer mouse also. These cause more problems than throwing. Vision and Eyesight Concerns Staring into a white hot kiln to see the cones may damage the eyes. Intense ultra violet (UV) and infra red (IR) light is emitted. Ordinary eye glasses or sunglasses may protect from some UV, but are not helpful for IR. Welding goggles used by electric arc welders or glasses specifically designed for kiln work are useful to reduce damaging rays. Eye damage is also reduced by staying as far back as possible from the kiln when looking into the kiln. Persons stoking a wood kiln need to take similar precautions to protect their eyes. "Research has shown that UV radiation increases the likelihood of certain cataracts." (5 - U.S. Environmental Portection Agency) Disclaimer - This page is in progress and posted by Marvin Bartel - There may be other hazards not included here, so just because something is not listed here, does NOT mean that it is safe to eat, drink, touch, or inhale. If you know of a ceramic hazard not mentioned here, please contact me. (1) Page 247, Frank and Janet Hamer. The Potter's Dictionary of Materials and Techniques. 1991. A & C Black Limited, London. (2) Alfred Franzblau, Elizabeth Hedgeman, Qixuan Chen, Shih-Yuan Lee, Peter Adriaens, Avery Demond, David Garabrant, Brenda Gillespie, Biling Hong, Olivier Jolliet, James Lepkowski, William Luksemburg, Martha Maier, and Yvan Wenger1 "Case Report: Human Exposure to Dioxins from Clay" Environ Health Perspect. 2008 February; 116(2): 238–242. (retrieved 3-10-2010) (3) (from NPR) "Potter Warren MacKenzie's Enduring Craft" (4) Monona Rossol. "Respirators & Dust Masks, Part 1."Nov/Dec 1999 issue of Clay Times. Respirators & Dust Masks, Part 2 Jan/Feb 2000 issue of Clay Times. (5) EPA "Health effects of UV overexposure." (retrieved 3-10-2010) The following articles cover topics in more depth in Clay Times magazine. Monona Rossol is the author of the following articles. All rights reserved. This page © Marvin Bartel. You may link to this page, but you may not post it on your site or publish it. Scholarly citations are allowed. They require attribution.
This page was updated June28, 2011 For permission to make copies or handouts, contact the author. |
